To fix some nits:
Right click desktop | personalize
Hit alt to show the menu
view | details
view | status bar
tools | folder options
general tab
view tab
always show menus → on
display the full path in the title bar → on
show hidden files, folders, and drives → on (if you want)
hide extensions for known file types → off
show preview handlers in preview pane → off (maybe)
right click recycle bin | properties
win+pause/break to get to system properties
Click Start, click Run, and type "control userpasswords2". This is a shortcut instead of having to click on Start → Control Panel → User Accounts.
Uncheck the "Users must enter a username and password to use this computer" check box.
Click Apply.
Enter the user name and password you wish to automatically log on with, and then click OK.
Click OK again and you're all done.
(from http://8help.osu.edu/2063.html)
Start, type "ease", select 'Ease of Access Center'.
Click 'Make the keyboard easier to use'.
Tick ‘Underline keyboard shortcuts and access keys’
If you don't want to see the libraries every time you open explorer, change the shortcut to:
%SystemRoot%\explorer.exe ,::{20D04FE0-3AEA-1069-A2D8-08002B30309D}